简历:
学习及工作经历
2021.11-至今 大象成视人3秒跳转视频,特聘研究员,博士生导师
2019.11-2021.10 德国维尔茨堡大学,博士后,合作导师:Holger Braunschweig 教授
2014.07-2019.09 新加坡南洋理工大学,博士后,合作导师:Rei Kinjo 教授
2010.09-2014.07 中国科学院大学,博士,导师:杨镜奎教授,吴海臣研究员
2007.09-2010.07 四川大学生物材料中心,硕士,导师:樊渝江教授
2003.09-2007.07 四川大学材料学院,学士
研究兴趣
我们主要关注主族元素新化合物(s区和p区元素),特别是低价态和低配位数主族元素化合物的合成、结构、成键,以及它们在小分子活化和转移,复杂化合物构建和催化反应中的机理和应用研究。研究兴趣包括:主族元素的极性反转;低价和低配位主族元素化合物的类过渡金属性质;结构新颖的主族元素卡宾、烯烃、炔烃和其它小分子类似物;弱配位离子;惰性化学键的活化等。
(课题组诚招研究生、研究助理以及联合培养学生,同时欢迎本科生进入实验室参与科研项目和完成毕业设计)
主要工作业绩
硼化合物被广泛应用于合成化学(硼氢化反应、Suzuki-Miyaura反应等)、材料科学(复合材料、功能高分子材料等)和生命医学领域(分子探针、肿瘤治疗等)。有机硼化合物缺电子硼中心的极性反转,赋予了硼原子碱性和亲核性,为研究元素间新化学键的控制形成和断裂,以及新化合物的合成,提供了新的思路和方法。以此为突破口,卢伟博士在博后期间先后研究了亲核性硼锂试剂、硼-金属键化合物、硼硼双键化合物及平面碳硼烷的合成、结构和化学性质,取得了一些创新性成果和突破性研究进展。相关成果以第一作者发表于J. Am. Chem. Soc.,Angew. Chem. Int. Ed.,Nat. Commun.和Chem. Sci.等期刊。其中两篇论文分别在2019年和2020年入选“JACS青年研究者虚拟专刊”。
主要奖励和荣誉
2019 SNIC Prof Lee Soo Ying Early Career Research Award (Gold) (新加坡)
代表性成果
1. An Unsymmetrical, Cyclic Diborene Based on a Chelating CAAC Ligand and its Small-Molecule Activation and Rearrangement Chemistry
Lu, W.; Jayaraman, A.; Fantuzzi, F.; Dewhurst, R. D.; Härterich, M.; Dietz, M.; Hagspiel, S.; Krummenacher, I.; Hammond, K.; Cui, J.; Braunschweig, H.*
Angew. Chem., Int. Ed. 2021, https://doi.org/10.1002/anie.202113947. (Selected as a hot paper)
![](/__local/A/88/CF/AD309E54B4A8138231CE9EE3CC7_0789246F_AC0B.jpg)
2. A flat carborane with multiple aromaticity beyond Wade–Mingos’ rules
Lu, W.; Dinh Cao Huan Do.; Kinjo, R.*
Nat. Commun. 2020, 11, 3370. (Highlighted as Editor's Focus in Nature Communications); (Featured in Nature Research Chemistry Community)
![](/__local/8/00/51/6D33CF5639BFF90BC3C7C552769_AF04BC32_12124.jpg)
3. Crystalline Tetraatomic Boron(0) Species
Lu, W.; Li, Y.; Kinjo, R.*
J. Am. Chem. Soc. 2019, 141, 5164–5168. (Highlighted in chemistryviews) (selected by JACS for JACS Young Investigators Virtual Issue 2020)
![](/__local/5/0F/36/58EEAA2AD8502689796479D919E_78FF3B02_68BD.jpg)
4. Facile Activation of Homoatomic σ Bonds in White Phosphorus and Diborane by a Diboraallene
Lu, W.; Xu, K.; Li, Y.; Hirao, H.; Kinjo, R.*
Angew. Chem., Int. Ed. 2018, 130, 15691-15695.
![](/__local/4/91/47/E44423FEA0286E0B3EEA114887F_DA16352C_1B145.jpg)
5. Boron Analogue of Vinylidene Dication Supported by Phosphines
Lu, W.; Li, Y.; Ganguly, R.; Kinjo, R.*
J. Am. Chem. Soc. 2018, 140, 1255–1258. (selected by JACS for JACS Young Investigators Virtual Issue 2019)
![](/__local/B/34/FC/140D1AA8F05B2FD4EB059883DBF_113950BB_11FE5.jpg)
6. Coordination of Asymmetric Diborenes towards Cationic Coinage Metals (Au, Ag, Cu)
Lu, W.; Kinjo, R.*
Chem. Eur. J. 2018, 24, 15656–15662.
![](/__local/A/8E/9A/10C85E6A0B523CBEBAC6D90DB57_58C93A7E_A809.jpg)
7. Complexation of Asymmetric Diborenes with Magnesium Bromide
Lu, W.; Kinjo, R.*
Chem. Commun. 2018, 54, 8842–8844.
![](/__local/1/60/B7/706D46CCD2E6AD1F91FD880398F_8DA1B16F_10A46.jpg)
8. Crystalline Neutral Allenic Diborene
Lu, W.; Li, Y.; Ganguly, R.; Kinjo, R.*
Angew. Chem., Int. Ed. 2017, 56, 9829–9832. (Selected as a hot paper)
![](/__local/7/0C/E9/C36745D4D8EF5DC59AE816838A4_649F3278_5F7D.jpg)
9. Alkene–Carbene Isomerization induced by Borane: Access to an Asymmetrical Diborene
Lu, W.; Li, Y.; Ganguly, R.; Kinjo, R.*
J. Am. Chem. Soc. 2017, 139, 5047–5050.
![](/__local/0/C6/A0/0F4524B4306A15041A26431CF7B_79CAE5F9_10532.jpg)
10. Isolation of 1,2,4,3-Triazaborol-3-yl-metal (Li, Mg, Al, Au, Zn, Sb, Bi) Derivatives and Reactivity toward CO and Isonitriles
Lu, W.; Hu, H.; Li, Y.; Ganguly, R.; Kinjo, R.*
J. Am. Chem. Soc. 2016, 138, 6650–6661.
![](/__local/7/3C/14/5C2F17A3BE74527A2AD55A944A8_8F7C56F2_7EB8.jpg)
11. Regioselective Alkyl Transfer from Phosphonium Ylides to Functionalized Polyfluoroarenes
Lu, W.; Gao, J.; Yang, J.;* Liu, L.; Zhao, Y.; Wu, H.*
Chem. Sci. 2014, 5, 1934-1939.
![](/__local/7/F3/7D/23A11C1C0A68046D7E0AA68746D_7BE1B69B_3144.jpg)
12. Formation of Boron-Main Group Element Bonds by Reactions with a Tricoordinate Organoboron L2PhB: (L = oxazol-2-ylidene)
Kong, L.; Lu, W.; Li, Y.;Ganguly, R.; Kinjo, R.*
Inorg. Chem. 2017, 56, 5586-5593.
13. Azaborabutadienes: Synthesis by Metal-free Carboboration of Nitriles and Utility as Building Blocks for B,N-heterocycles
Kong, L.; Lu, W.; Li, Y.;Ganguly, R.; Kinjo, R.*
Angew. Chem., Int. Ed. 2016, 55, 14718-14722.
14. Isolation of a Diborane(6) Dication: Formation and Cleavage of an Electron-Precise B(sp3)-B(sp3) Bond
Kong, L.; Lu, W.; Li, Y.;Ganguly, R.; Kinjo, R.*
J. Am. Chem. Soc. 2016, 138, 8623–8629.